Friedrich Wöhler

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Friedrich Wöhler
German chemist
German chemist
Born 31 July 1800(1800-07-31)
Eschersheim, Frankfurt am Main, Germany
Died 23 September 1882 (aged 82)
Göttingen, Germany
Residence Germany
Nationality German
Fields Organic chemistry
Biochemistry
Institutions Polytechnic School in Berlin
Polytechnic School at Kassel
University of Göttingen
Doctoral advisor Leopold Gmelin
Jöns Jakob Berzelius
Doctoral students Heinrich Limpricht
Rudolph Fittig
Adolph Wilhelm Hermann Kolbe
Georg Ludwig Carius
Albert Niemann
Vojtěch Šafařík
Carl Schmidt (chemist)
Theodor Zincke
Known for Wöhler synthesis of urea

Friedrich Wöhler (31 July 1800 - 23 September 1882) was a German chemist, best-known for his synthesis of urea, but also the first to isolate several chemical elements.

Contents

[edit] Early days

He was born in Eschersheim, nowadays a district of Frankfurt am Main. In 1823 Wöhler finished his study of medicine in Heidelberg at the laboratory of Leopold Gmelin, who arranged for him to work under Jöns Jakob Berzelius in Stockholm. He taught chemistry from 1826 to 1831 at the Polytechnic School in Berlin until 1839 when he was stationed at the Higher Polytechnic School at Kassel. Afterwards, he became Ordinary Professor of Chemistry in the University of Göttingen, where he remained until his death in 1882.

[edit] Contributions to chemistry

Wöhler is regarded as a pioneer in organic chemistry as a result of him (accidentally) synthesizing urea in the Wöhler synthesis in 1828.[1] This synthesis was a landmark in the history of Science which disproved and undermined the Vital Force Theory which was believed for centuries, by showing that organic compounds could be synthesized from inorganic materials.

[edit] Major works, discoveries and research

Friedrich Wöhler circa 1850s.

Wöhler was also known for being a co-discoverer of beryllium, silicon and silicon nitride[2] , as well as the synthesis of calcium carbide, among others. In 1834, Wöhler and Liebig published an investigation of the oil of bitter almonds. They proved by their experiments that a group of carbon, hydrogen, and oxygen atoms can behave like an element, take the place of an element, and can be exchanged for elements in chemical compounds. Thus the foundation was laid of the doctrine of compound radicals, a doctrine which had a profound influence on the development of chemistry.

Since the discovery of potassium by Humphry Davy, it had been assumed that alumina, the basis of clay, contained a metal in combination with oxygen. Davy, Oerstedt, and Berzelius attempted the extraction of this metal, but failed. Wöhler then worked on the same subject, and discovered the metal aluminium. To him also is due the isolation of the elements yttrium, beryllium, and titanium, the observation that "silicium" (silicon) can be obtained in crystals, and that some meteoric stones contain organic matter. He analyzed a number of meteorites, and for many years wrote the digest on the literature of meteorites in the Jahresbericht der Chemie; he possessed the best private collection of meteoric stones and irons existing. Wöhler and Sainte Claire Deville discovered the crystalline form of boron, and Wöhler and Buff the hydrogen compounds of silicon (the silanes) and a lower oxide of the same element. Wohler also prepared urea, a constituent of urine, from ammonium cyanate in the laboratory without the help of a living cell.

[edit] Final days and legacy

Wöhler's discoveries had great influence on the theory of chemistry. The journals of every year from 1820 to 1881 contain contributions from him. It was remarked that "for two or three of his researches he deserves the highest honor a scientific man can obtain, but the sum of his work is absolutely overwhelming. Had he never lived, the aspect of chemistry would be very different from that it is now."[citation needed]

While sojourning at Cassel, Wöhler made, among other chemical discoveries, one for obtaining the metal nickel in a state of purity, and with two friends he founded a factory there for the preparation of the metal.

Wöhler had several students who became notable chemists. Among them were Georg Ludwig Carius, Heinrich Limpricht, Rudolph Fittig, Adolph Wilhelm Hermann Kolbe, Albert Niemann, and Vojtěch Šafařík.

[edit] Works

  • Lehrbuch der Chemie, Dresden, 1825, 4 vols.
  • Grundriss der Anorganischen Chemie, Berlin, 1830
  • Grundriss der Organischen Chemie, Berlin, 1840
  • Praktische Übungen in der Chemischen Analyse, Berlin, 1854

[edit] References

  • Brigitte Hoppe (2007). "Review of The life and work of Friedrich Wohler (1800-1882) by Robin Keen, edited by Johannes Buttner". Isis 98 (1): 195–196. doi:10.1086/519116. 
  • George B. Kauffman, Steven H. Chooljian (2001). "Friedrich Wöhler (1800–1882), on the Bicentennial of His Birth". The Chemical Educator 6 (2): 121–133. doi:10.1007/s00897010444a. 
  1. ^ Friedrich Wöhler (1828). "Ueber künstliche Bildung des Harnstoffs". Annalen der Physik und Chemie 88 (2): 253–256. doi:10.1002/andp.18280880206. http://gallica.bnf.fr/ark:/12148/bpt6k15097k/f261.chemindefer. 
  2. ^ Deville, H. and Wohler, F. (1857). "Erstmalige Erwahnung von Si3N4". Liebigs Ann. Chem. 104: 256. 
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