File:Fig. 2 Illustration to the origin of the PJTE as due to added covalence bonding by distortion.tif
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Summary
| Description |
English: Illustration to the origin of the pseudo Jahn-Teller effect as due to added covalence bonding by distortion: (a) when the Fe atom in metall porphyrins is in the porphyrin-ring in-plane position, the net overlap of its dz2 orbital with the near-neighbor nitrogen pz orbitals is zero by symmetry, and these orbitals do not contribute to the bonding; (b) the out-of-plane displacement of Fe results in their non-zero overlap producing a covalence contribution to the bonding |
| Date | |
| Source | Own work |
| Author | BorisBella |
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File history
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| Date/Time | Thumbnail | Dimensions | User | Comment | |
|---|---|---|---|---|---|
| current | 22:52, 22 January 2017 |  | 413 × 318 (28 KB) | BorisBella | Illustration to the origin of the PJTE as due to added covalence bonding by distortion: (a) when the Fe atom in metalloporphyrins is in the porphyrin-ring in-plane position, the net overlap of its dz2 orbital with the near-neighbor nitrogen pz orbitals... |
| 21:38, 22 January 2017 |  | 413 × 318 (28 KB) | BorisBella | Cropped away a border, eliminated white space | |
| 18:54, 21 January 2017 |  | 1,152 × 648 (33 KB) | BorisBella | User created page with UploadWizard |
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