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Vladimir M. Shalaev
Born (1957-02-18) February 18, 1957 (age 67)
Krasnoyarsk, Russia
CitizenshipUnited States, Russia
Alma materKrasnoyarsk State University, Russia
Scientific career
Fields
InstitutionsPurdue University
Websiteengineering.purdue.edu/~shalaev/

Vladimir Shalaev (born February 18, 1957) is an American physicist of Russian descent known for his work in the fields of nanophotonics, plasmonics, and optical metamaterials[1][2][3][4]. Vladimir (Vlad) M. Shalaev is currently the Robert and Anne Burnett Distinguished Professor of Electrical and Computer Engineering[5], Professor of Biomedical Engineering[6] and Professor of Physics[7] at Purdue University. Prof. Shalaev also serves as Scientific Director for Nanophotonics at Purdue University's Birck Nanotechnology Center[8].

Career[edit]

1980s

Shalaev received a Master of Science Degree in physics in 1979 from Krasnoyarsk State University (Russia) and a PhD Degree in physics and mathematics in 1983 from the same University. His doctoral work involved theoretical analysis of resonant interaction of laser radiation with gaseous media, in particular i) Doppler-free multi-photon processes and their applications in nonlinear optics[9], spectroscopy[10] and laser physics[11], and ii) the (newly-discovered then) phenomenon of light-induced drift of gases[12] (here and thereafter, only selected, representative papers of Shalaev are cited; for complete list of Shalaev's publications visit his website[13]).

In 1983 Shalaev joined the Faculty of Krasnoyarsk State University, Dept. of Physics, and research staff of L.V. Kirensky Institute of Physics (Krasnoyarsk, Russia)[14] where he conducted research in the area of i) resonant nonlinear optics of gaseous media[15], ii) light-induced gas kinetics[16], and iii) linear optics and (impurity) optical non-linearities of fractal objects, such as fractal clusters and rough films[17][18]. In their collaborative work[17], Shalaev and M. Stockman were the first to point out that in clusters formed by conducting nano-particles, fractal geometry underlies sharp localization of light-induced electron-density oscillation modes – surface plasmons. In the nanometer-sized plasmon confinement areas, colloquially known as “hot spots”, the amplitude of the (oscillatory) local electric field can exceed that of the applied external field by several orders of magnitude. This local field enhancement in turn leads to greatly amplified optical responses from impurity particles bound to a fractal cluster resulting in i) giant Raman scattering[17] and ii) enhanced non-linear optical phenomena, including Coherent Anti-Stokes Raman Scattering (CARS) and degenerate-four-wave-mixing-based Optical Phase Conjugation[18]. Generation of higher optical harmonics was also found to be enhanced, although to a lesser extent[18].

1990s

In 1990 Shalaev was awarded a Humboldt Foundation Fellowship and, as a Humboldt Fellow, in 1990-1991 he continued his research into optics of fractal media at the Heidelberg University in Germany and at the Paris-Sud University in France[19][20][21]. In work [19], inherent optical non-linearity of metal fractal clusters (in contrast with that of impurity particles adsorbed on cluster's monomers[18]) was investigated theoretically and experimentally, and the conclusion was reached that degenerate four-wave mixing/optical phase-conjugation was enhanced by six orders of magnitude as a result of aggregation of silver nano-particles into fractal clusters. The authors themselves summed up their findings as follows: "The studies of metal fractal clusters have shown them to Ье а promising nonlinear optical medium with а unique comЬination of the following properties: giant non-linearity, rapid response, broadbandness and spatial-frequency-polarization selectivity of interaction with radiation"[19].

In 1991-1993 Shalaev carries on his studies as a Research Associate Professor at University of Toronto (Canada), Department of Chemistry[22][23].

In 1993 Shalaev joins the Faculty of New Mexico State University, Department of Physics (Las Cruses, New Mexico, USA). Research carried out in this period includes developing theory of giant Raman scattering from semi-continuous metal films[24][25] and surface-enhanced optical non-linearities of such films, in particular those responsible for the optical Kerr-effect, four-wave mixing, second and third-harmonic generation[26]. The nonlinear optical signals had been found to come from nm-sized areas corresponding to the plasmon modes of the film. It was established that near the percolation threshold of a semi-continuous metal film, Raman scattering from the molecules absorbed on the surface of the film is enhanced on average by more than six orders of magnitude. The enhancement is associated with excitation of collective electromagnetic eigenmodes of the film which have the geometrical form of spatially separated sharp, large-amplitude peaks of the local field strength, which the authors refer to as field fluctuations.

2000s - present

In 2001, Shalaev joins the Faculty of Purdue University, where he serves now as Bob and Anne Burnett Distinguished Professor of Electrical and Computer Engineering[5].

Significant part of the research carried out by Shalaev since early 2000s until the present time involved optical metamaterials (MMs). Optical MMs are artificial, nanostructured media (typically containing a metallic/plasmonic component) that display unique optical properties (so far) not observed in naturally occurring materials. One of the most spectacular features of optical MMs that can be achieved through deliberate design is negative index of refraction, and the resulting exotic optical media are referred to as negative-index metamaterials (NIMs)[27]. Prospective applications for NIMs include superlens capable of imaging objects and fine geometrical features that are much smaller in size than the wavelength of light, optical nanolithography and nanocircuits, and metacoatings that can render objects invisible[28]. Shalaev with co-workers were among the first to experimentally realize a NIM[29]. They achieved a negative index of refraction of -0.3 at the optical telecommunication wavelength, 1.5μm, using a double-periodic array of gold nano-rods: the value of the refractive index was inferred from experimental data on amplitudes and phases of reflected and transmitted light.

One possible approach to engineering negative index of refraction, which was taken by the authors of [29], involves strong magnetic response of the material at optical frequencies. Generally, the response of naturally occurring materials to the magnetic component of electromagnetic waves at optical frequencies is weak compared to their response to the electric component. Various metamaterial-based approaches have been employed to produce strong, resonant optical magnetism, thus extending and enhancing light-matter interactions. Shalaev with co-workers experimentally demonstrated nanostructured composits displaying strong magnetic response across the whole visible spectrum[30]. They employed metamaterials consisting of arrays of paired thin silver strips and used geometrical parameters of the nanostructure to control its resonant magnetic properties.

Electromagnetic energy dissipation in the metallic part of metamaterial nanostructure has been a major obstacle hindering technological application of metamaterials. Shalaev with co-workers were the first to experimentally demonstrate the principal  possibility of compensating for energy dissipation in NIMs through incorporation into the metamaterial design of an optical gain medium[31].

Shalaev made a significant contribution to transformation optics (TO) - a new branch of electromagnetism which is based on the form-invariance of Maxwell's equations under coordinate transformations (provided the electric permittivity and magnetic permeability of the medium are appropriately transformed)[32][33][34]. TO provides the means for engineering inhomogeneous, metamaterial-based optical media where light propagates in a predefined, almost arbitrary prescribed manner[35]. Shalaev contributed original designs of some of the most important TO devices: "invisibility cloak" - a device which guides light around itself, making the “cloak” and an object inside it invisible[36], a hyperlens magnifying nanometer-scale geometrical detail and producing a viewable far-field image, and light concentrator performing the opposite function - effectively collecting light and focusing it into nano-scale spatial domains[35].

Prof. Shalaev with co-workers, most notably - Prof. A. Boltasseva, were among the first to recognize the importance of introducing new plasmonic materials that would help bring to fruition the promise of plasmonics and metamaterials to give rise to a new generation of integrated optical and optoelectronic devices [### priority ref. is needed ###]. They drew the attention of researchers in the field to the opportunities afforded by alternative materials (other than conventional metals such as gold and silver traditionally employed in the field of plasmonics and metamaterials) that exhibit metallic properties and possess significant advantages over noble metals in terms of proposed device performance, design flexibility, component fabrication, system integration, and device tunability[37]. One promising class of alternative plasmonic materials comprises the so-called Transparent Conducting Oxides (TCOs), exemplified by such compounds as indium tin oxide (ITO), and  doped - for example, with gallium or aluminum - zinc oxide (ZnO) and cadmium oxide (CdO). The metal-like properties of dopant electrons in TCOs underlie their ability to sustain surface plasmons similar to those in noble metals but at lower frequencies: in the near- to mid-infrared spectral range. The advantageous distinctive features of TCOs include their compatibility with modern semiconductor technology (for example, ITO is widely used in production of solar panels and flat-panel displays), tunable optical properties (variable e.g. by changing the dopant concentration), and chemical and mechanical stability [37][38][39][40]. Another promising class of alternative plasmonic materials for the visible and lower-frequency spectral ranges consists of transition metal- (titanium-, zirconium-, tantalum-, etc.) nitrides. These materials are electronically conductive and the carrier concentration in these compounds can be varied, e.g. through the material composition or film deposition conditions, which allows for tuning their optical properties to meet the requirements of a particular device or application [37]. Another important advantage of these ceramic materials over noble metals is that they are refractory: they retain their thermal stability up to and above 2,000 Co [37], which makes them promising candidates to fulfill the demands of high-temperature plasmonic applications, e.g. electric power generation through thermophotovoltaics[41].

Shalaev made a significant contribution to the development of the field of optical metasurfaces – planar (thinner than the wavelength of light), laterally nano-structured metamaterials with unique optical properties[42][43][44]. Planar geometry of metasurfaces allows for easier component fabrication and integration in comparison with 3D, multilayer metamaterials, making metasurfaces promising functional components for nanophotonics and optoelectronics[45]. It was first demonstrated for the mid-infrared (mid-IR) wavelength of 8μm that special nanoantenna-array metasurfaces create phase discontinuities for the electromagnetic waves passing through them and drastically change the flow of reflected and refracted light[42]. This phenomenon was then extended to the near-IR wavelength region, and it was shown that the phenomenon is robust and exists in a wide spectral range[43]. The research that followed yielded various metasurface-based, "flat" optical components, including waveplates, lenses, holograms, and ultra-thin light absorbers[46][47][48][44].

Shalaev was among the group of researchers who were the first to experimentally demonstrate the spaser – a device analogous to laser, but generating coherent surface-plasmon field instead of light [49][50]. In contrast to conventional lasers, the size of a spaser is not limited from below by the wavelength of light, making spaser a promising coherent optical source for nanophotonics. The spaser developed by Shalaev with co-workers used a 44 nm core-shell nanostructure with gold core as the plasmonic resonator (providing optical feedback necessary for lasing/spasing) and a dye–doped silica shell as the optical gain medium [50]. Outcoupling of surface plasmon oscillations in this system to photonic modes made it essentially a single-particle nanolaser.

One of the areas where Prof. Shalaev and his colleagues at Purdue University and elsewhere have recently intensified their research efforts is plasmon-enhanced heterogeneous photocatalysis[51][52]. One of the central ideas in this field is to utilize hot electrons generated in the process of surface plasmon decay to populate carefully selected orbitals of molecules absorbed on the surface of plasmonic nanostructures. Resultant transient negative-ion states of the absorbates facilitate the rate-limiting step of the desired chemical reaction. This approach offers an opportunity to selectively enhance preferred chemical pathways while inhibiting the alternatives [51].

Awards and honors[edit]

Prof. Shalaev received a number of awards for his research and leadership in the field of nanophotonics and metamaterials, including

  • The 2015 IEEE Photonics Society William Streifer Scientific Achievement Award “for seminal contributions both to the theoretical framework and to the ground-breaking experimental realization of optical metamaterials” [3],
  • 2015 Rolf Landauer International ETOPIM Association Medal. According to the ETOPIM website, "the medal is awarded to honour senior scientists with pioneering contributions in the study of inhomogeneous media". [53]
  • The 2012 UNESCO Medal for the Development of Nanosciences and Nanotechnologies [1],
  • The 2010 Willis E. Lamb Award for Laser Science and Quantum Optics "for pioneering studies of optical metamaterials and plasmonic nanostructures" [2],
  • The 2010 Optical Society of America Max Born Award "for seminal contributions to both the theoretical framework and the experimental realization of optical metamaterials" [54],
  • Honorary Doctorate from University of Southern Denmark [55].

V. Shalaev is a Fellow of

Publications[edit]

Prof. V. Shalaev co-/authored three- [61] [62] [63] and co-/edited four [64] [65] [66] [67] books in the area of his scientific expertise. According to Prof. Shalaev's website, over the course of his career he contributed 28 invited chapters to various scientific anthologies and published a number of invited review articles, over 400 publications in total, including 277 research papers in refereed journals [68]. He is also a co-inventor in 20 patents [68], and he made over 300 invited presentations at International Conferences and leading research centers, including a number of plenary and keynote talks [69] [70].

References[edit]

  1. ^ a b 2012 UNESCO Medal for the Development of Nanosciences and Nanotechnologies
  2. ^ a b The 2010 Willis E. Lamb Award for Laser Science and Quantum Optics
  3. ^ a b The 2015 IEEE Photonics Society William Streifer Scientific Achievement Award
  4. ^ The 2010 Optical Society of America Max Born Award
  5. ^ a b People, School of Electrical and Computer Engineering, Purdue University
  6. ^ People, Weldon School of Biomedical Engineering, Purdue University
  7. ^ People, Department of Physics and Astronomy, Purdue University
  8. ^ Birck Nanotechnology Center Faculty
  9. ^ A. K. Popov, V. M. Shalaev, Doppler-free transitions induced by strong double-frequency optical excitations, Optics Communications, v.35, pp.189-193 (1980).
  10. ^ A. K. Popov, V. M. Shalaev, Doppler-free spectroscopy and wave-front conjugation by four-wave mixing of nonmonochromatic waves, Applied Physics, v.21, pp.93-94 (1980).
  11. ^ A. K. Popov, V. M. Shalaev, Unidirectional Doppler-Free Gain And Generation In Optically Pumped Lasers, Applied Physics B, v. 27,pp. 63-67 (1982).
  12. ^ A .K. Popov, A. M. Shalagin, V. M. Shalaev, V. Z. Yakhnin, Drift of gases induced by nonmonochromatic light, Applied physics, v.25, pp.347-350 (1981).
  13. ^ "Prof. Shalaev, Purdue University, Electrical & Computer Engineering". engineering.purdue.edu. Retrieved 2016-06-06.
  14. ^ Kirensky Institute of Physics, Siberian Branch of (then) USSR Scademy of Sciences
  15. ^ L. T. Bolotskikh, V. G. Popkov, A. K. Popov, V. M. Shalaev, Self-Diffraction of CO2-Laser Radiation in SF6, Optical and Quantum Electronics, v. 18, pp.115-121 (1986).
  16. ^ V. M. Shalaev and V. Z. Yakhnin, LID sound generated by pulsed excitation in gases, Journal of Physics B: Atomic and Molecular Physics, v.20, pp.2733-2743 (1987).
  17. ^ a b c V. M. Shalaev, M. I. Stockman, Fractals: optical susceptibility and giant Raman scattering, Zeitschrift für Physik D Atoms, Molecules and Clusters v.10, pp.71-79 (1988).
  18. ^ a b c d A.V. Butenko, V.M. Shalaev, M.I. Stockman, Fractals: giant impurity nonlinearities in optics of fractal clusters, Zeitschrift für Physik D - Atoms, Molecules and Clusters, v.10, pp.81-92 (1988).
  19. ^ a b c A. V. Butenko et. al., Nonlinear optics of metal fractal clusters, Zeitschrift für Physik D Atoms, Molecules and Clusters, v.990, pp. 283-289 (1990).
  20. ^ V. M. Shalaev et. al., Resonant light scattering by fractal clusters, Physical Review B, v.44, pp.12216-12225 (1991).
  21. ^ V. M. Shalaev, Mark I. Stockman, and R. Botet, Resonant excitations and nonlinear optics of fractals, Physica A, v.185, pp.181-6 (1992).
  22. ^ M. I. Stockman et. al., Enhanced Raman scattering by fractal clusters: Scale-invariant theory, Physical Review B, v.46, pp. 2821-2830 (1992).
  23. ^ D. P. Tsai et. al., Photon Scanning Tunneling Microscopy Images of Optical Excitations of Fractal Metal Colloid Clusters, Physical Review Letters, v.72, pp. 4149-4152 (1994).
  24. ^ F. Brouers et al., Theory of giant Raman scattering from semicontinuous fims, Physical Review B v.55, pp.13234-13245 (1997).
  25. ^ V. M. Shalaev, Electromagnetic Properties of Small-Particle Composites, Physics Reports, v.272, pp.61-137 (1996).
  26. ^ V. M. Shalaev and A. K. Sarychev, Nonlinear optics of random metal-dielectric films, Physical Review B, v.57, pp.13265-13288 (1998).
  27. ^ Shalaev, V. M. Optical Negative-Index Metamaterials, Nature photonics v.1, pp.41-48 (2007)
  28. ^ W. Cai, U.K. Chettiar, A.V. Kildishev & V.M. Shalaev, Optical cloaking with metamaterials, Nature Photonics, v.1, pp.224-227 (2007)
  29. ^ a b V.M. Shalaev, W. Cai, U.K. Chettiar, H.-K. Yuan, A.K. Sarychev, V.P. Drachev, and A.V. Kildishev, Negative Index of Refraction in Optical Metamaterials, Optics Letters 30, pp.3356-3358 (2005)
  30. ^ W. Cai et al., Metamagnetics with rainbow colors, Optics Express, v.15, pp.3333-41 (2007)
  31. ^ S.Xiao, V.P. Drachev, A.V. Kildishev, X. Ni, U.K. Chettiar, H.-K. Yuan, and V.M. Shalaev, Loss-free and active optical negative-index metamaterials, Nature 466, 735-738 (2010).
  32. ^ J. B. Pendry, D. Schurig, and D. R. Smith, Controlling electromagnetic fields, Science v.312, pp.1780–1782 (2006)
  33. ^ V.M. Shalaev, Transforming Light , Science, v.322, pp.384-86 (2008)
  34. ^ F. Sun, B. Zheng, H. Chen, W. Jiang, S. Guo, Y. Liu, Y. Ma, S. He, Transformation Optics: From Classic Theory and Applications to its New Branches, Laser & Photonics Reviews, v.11, p. 1700034 (2017)
  35. ^ a b A.V. Kildishev and V.M. Shalaev, Transformation optics and metamaterials, Phys.-Usp. v.54, pp.53 (2011).
  36. ^ W. Cai, U. K. Chettiar, A. V. Kildishev, and V. M. Shalaev, Optical cloaking with metamaterials, Nature Photonics, v.1, pp.224–227 (2007).
  37. ^ a b c d G.V. Naik, V.M. Shalaev, and A. Boltasseva, Alternative Plasmonic Materials: Beyond Gold and Silver, Advanced Materials, v.25, pp.3264–3294 (2013).
  38. ^ Y. Wang, A. Capretti, and L. Dal Negro, Wide tuning of the optical and structural properties of alternative plasmonic materials, Optical Materials Express, vol. 5, pp. 2415–2430 (2015).
  39. ^ J. B. Khurgin and A. Boltasseva, Reflecting upon the losses in plasmonics and metamaterials, MRS Bulletin, v.37, pp.768–779 (2012)
  40. ^ J. Kim, G. V. Naik, A. V. Gavrilenko, K. Dondapati, V. I. Gavrilenko, S. M. Prokes, O. J. Glembocki, V. M. Shalaev, and A. Boltasseva, Optical properties of gallium-doped zinc oxide—A low-loss plasmonic material: First-principles theory and experiment, Phys. Rev. X, v.3, p.041037 (2013)
  41. ^ U. Guler, A. Boltasseva, and V. M. Shalaev, Refractory plasmonics, Science, v. 344, pp. 263–264 (2014)
  42. ^ a b N. Yu, P. Genevet, M. A. Kats, F. Aieta, J.-P. Tetienne, F. Capasso, and Z. Gaburro, Light propagation with phase discontinuities: Generalized laws of reflection and refraction, Science, v.334, pp. 333–337 (2011)
  43. ^ a b X. Ni, N. K. Emani, A. V. Kildishev, A. Boltasseva, and V. M. Shalaev, Broadband light bending with plasmonic nanoantennas, Science, v. 335, pp. 427 (2012)
  44. ^ a b N. Yu, and F. Capasso, Optical Metasurfaces and Prospect of Their Applications Including Fiber Optics, Journal Of Lightwave Technology, v. 33, pp.2344-2358 (2015)
  45. ^ A. V. Kildishev, A. Boltasseva, and V. M. Shalaev, Planar photonics with metasurfaces, Science, v.339, 1232009 ( 2013) )
  46. ^ F. Ding, Z. Wang, S. He, V. M. Shalaev, and A. V. Kildishev, Broadband high-efficiency half-wave plate: A supercell-based plasmonic metasurface approach, ACS Nano, vol. 9, pp. 4111-4119, 2015
  47. ^ X. Ni, S. Ishii, A. V. Kildishev, and V. M. Shalaev, Ultra-thin, planar, Babinet-inverted plasmonic metalenses, Light: Science & Applications., v.2, p.e72 (2013)
  48. ^ X. Ni, A. V. Kildishev, and V. M. Shalaev, Metasurface holograms for visible light, Nature Commun., v.4, pp.1-6 (2013)
  49. ^ Malin Premaratne, and Mark I. Stockman, Theory and Technology of SPASERs, Advances In Optics And Photonics, v. 9, pp. 79-128 (2017)
  50. ^ a b M. A. Noginov, G. Zhu, A. M. Belgrave, R. Bakker, V. M. Shalaev, E. E. Narimanov, S. Stout, E. Herz, T. Suteewong and U. Wiesner, Demonstration of a spaser-based nanolaser, Nature v. 460, pp.1110-1112 (2009)
  51. ^ a b A. Naldoni et. al., Applying plasmonics to a sustainable future, Science, Vol. 356, Issue 6341, pp. 908-909 (2017).
  52. ^ A. Naldoni, F. Riboni, U. Guler, A. Boltasseva, V. M. Shalaev, A. V. Kildishev, Solar-powered plasmon-enhanced heterogeneous catalysis , Nanophotonics 5 (1) 112–133 (2016).
  53. ^ Rolf Landauer International ETOPIM Association Medal
  54. ^ The 2010 Optical Society of America Max Born Award
  55. ^ Professor Vladimir Shalaev receives Honorary Doctorate Degree from University of Southern Denmark, Purdue, Engineering, ECE, Homepage Spotlights, November 5, 2015
  56. ^ APS Fellow Archive
  57. ^ Complete List of SPIE Fellows
  58. ^ 2003 OSA Fellows
  59. ^ 2015 MRS Fellows
  60. ^ IEEE Fellows Directory
  61. ^ W. Cai, V. Shalaev, Optical Metamaterials: Fundamentals and Applications, Springer, 2010
  62. ^ A. K. Sarychev, V. M. Shalaev, Electrodynamics of Metamaterials, World Scientific, 2007
  63. ^ V. M. Shalaev, Nonlinear Optics of Random Media: Fractal Composites and Metal-Dielectric Films, Springer, 2000
  64. ^ S. Kawata, V. M. Shalaev (editors), Tip Enhancement, Elsevier, 2007
  65. ^ S. Kawata, V. M. Shalaev (editors), Nanophotonics with Surface Plasmons, Elsevier, 2007
  66. ^ V. M. Shalaev (editor), Optical Properties of Nanostructured Random Media, Springer, 2002
  67. ^ V. M. Shalaev, M. Moskovits (editors), Nanostructured Materials: Clusters, Composites, and Thin Films, American Chemical Society, 1997
  68. ^ a b List of Prof. V. Shalaev's website: Publications
  69. ^ Prof. V. Shalaev's website: Coference Talks
  70. ^ Prof. V. Shalaev's website: Invited Lectures



Category:American physicists Category:Russian physicists Category:1957 births Category:Living people Category:Optical physicists Category:Metamaterials scientists Category:Purdue University faculty Category:Fellows of the American Physical Society Category:Fellows of the Optical Society Category:Fellows of SPIE

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