From Wikipedia, the free encyclopedia
Antimonide chlorides or chloride antimonides are compounds containing anions composed of chloride (Cl−) and antimonide (Sb3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the antimonide bromides, antimonide iodides, phosphide bromides, and arsenide bromides.
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system
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space group
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unit cell Å
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density
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R3c
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| SbHg2AlCl4
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orthorhombic
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Pbcn
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a = 11.9771, b = 8.7826, c = 17.5237, Z=8
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1843.3
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red; room temp; air sensitive
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[1]
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| SbHg2AlCl4
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orthorhombic
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Pna21
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a = 11.9529, b = 8.7536, c = 17.4532, Z=8
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1826.1
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red; low temp
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[1]
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| [SbHg2]GaCl4
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orthorhombic
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Pbcn
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a = 12.0023, b = 8.7615, c = 17.5083, Z = 8
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>277K
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[2]
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| [SbHg2]GaCl4
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orthorhombic
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Pna21
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a = 17.4330, b = 8.7436, c = 11.9692, Z=8
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<277
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[2]
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| (Sb2Te2)[AlCl4]
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triclinic
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P1
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a = 9.4930, b = 13.4824, c = 18.0497, α = 78.983, β = 88.060, γ = 88.444°, Z = 8
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2239.65
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red
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[3]
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Thioantimonate chlorides[edit]
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Selenoantimonate chlorides[edit]
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References[edit]
