User:Graeme Bartlett/fluoride borate

From Wikipedia, the free encyclopedia

Before adding here, consider Borate fluoride

A fluoride borate is a chemical compound containing both fluoride ions and borate ions. The fluorine atoms are not bound to the boron as in fluoroborates or fluorooxoborates.

  • .
  • Gd4(BO2)O5F Space group Pmmn a=15.746 b=3.8142 c=6.609 V=396.9 Z=2 D=6.45 colourless
  • Gd2(BO3)F3
  • Gd3(BO3)2F3
  • Gd4[B4O11]F2
  • Eu5(BO3)3F
  • Ba5(BO3)3F

List[edit]

name formula ratio

BO3:F

mw system space group unit cell Å volume density optical discover references
Arrheniusite-(Ce) CaMg[(Ce7Y3)Ca5](SiO4)4(Si2B3AsO18)(BO3)F11 4:11 trigonal R3m a = 10.8082 c = 27.5196 2,784.1 2019 [1]
Berborite Be2(BO3)(OH,F) · H2O ~1:1 trigonal P3 a = 4.434 c = 5.334 90.82 Uniaxial (-) nω = 1.580 nε = 1.485

Max birefringence: δ = 0.095

1967 [2]
Britvinite [Pb7(OH)3F(BO3)2(CO3)][Mg4.5(OH)3(Si5O14)] triclinic P1 a = 9.3409 b = 9.3579 c = 18.833

α = 80.365°, β = 75.816°, γ = 59.870° Z=2

1378.7 5.51 Biaxial (-) nα = 1.896 nβ = 1.903 nγ = 1.903

2V: measured: 20°

Max birefringence: δ = 0.007

2006 [3]
Byzantievite Ba5(Ca,REE,Y)22(Ti,Nb)18(SiO4)4[(PO4, SiO4)]4(BO3)9O22[(OH),F]43(H2O)1.5 ~9:43 trigonal R3 a = 9.1202 c = 102.145 7,357.4 4.10 Uniaxial (-) nω = 1.940 nε = 1.860(5)

Max birefringence: δ = 0.080

2009 [4]
Cappelenite-(Y) Ba(Y,Ce)6Si3B6O24F2 6:2 trigonal P3 a = 10.67 c = 4.68 Z=1 461.4 4.407 Uniaxial 1884 [5]
Fluoborite Mg3(BO3)(F,OH)3 ~1:3 hexagonal a = 8.8 c = 3.1 208 Uniaxial (-) nω = 1.570 nε = 1.534

Max birefringence: δ = 0.036

1926 [6]
Fluor-buergerite Na(Fe3+3)Al6(Si6O18)(BO3)3O3F 3:1 trigonal R3m a = 15.87 c = 7.18 Z=3 1,566 Uniaxial (-) nω = 1.735 nε = 1.655

Max birefringence: δ = 0.080

1966 [7]
Fluor-dravite Na(Mg3)Al6(Si6O18)(BO3)3(OH)3F 3:1 trigonal R3m a = 15.955 c = 7.153 Z=3 1576.9 3.120 Uniaxial (-) nω = 1.645 nε = 1.621

Max birefringence: δ = 0.024

2011 [8]
Fluor-elbaite Na(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3F 3:1 trigonal R3m a = 15.8933 c = 7.1222 Z=3 1558.02 Uniaxial (-)

Pleochromatic light green/blue green

2011 [9]
Fluor-feruvite Ca(Fe2+)3MgAl5(Si6O18)(BO3)3(OH)3F 3:1 trigonal R3m Z=3 2008 [10]
Fluor-liddicoatite Ca(Li2Al)Al6(Si6O18)(BO3)3(OH)3F 3:1 trigonal R3m a = 15.875 c = 7.126 Z=3 1,555.3 3.02 Uniaxial (-) nω = 1.637 nε = 1.621

Max birefringence: δ = 0.016

2011 [11]
Fluor-schorl Na(Fe2+3)Al6(Si6O18)(BO3)3(OH)3F 3:1 trigonal R3m a = 16.005 c = 7.176 Z=3 1,591.9 Uniaxial (-) nω = 1.660 - 1.661 nε = 1.636 - 1.637

Max birefringence: δ = 0.024

2011 [12]
Fluor-tsilaisite Na(Mn2+)3Al6(Si6O18)(BO3)3(OH)3F 3:1 trigonal R3m a = 15.9398 c = 7.1363 Z=3 1570.3 3.134 Uniaxial (-) 2012 [13]
Fluor-uvite CaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3F 3:1 trigonal R3m a = 15.954 c = 7.214 Z=3 1590 3.08 Uniaxial nω = 1.637 - 1.668 nε = 1.619 - 1.639

Max birefringence: δ = 0.018 - 0.029

2010 [14]
Hellandite-(Yb) (Ca,Y)4(Yb,Y)2(Al,Fe3+,Ti4+)(Be,Li)2[B4Si4O22](O,F,OH)2 4:2 [15]
Jeremejevite Al6B5O15(F,OH)3 1:1 Hexagonal P63/m a = 8.5591 c = 8.1814 Z=2 519.06 3.28 Uniaxial (-) nω = 1.653 nε = 1.640

Max birefringence: δ = 0.013

1883 [16]
Laptevite-(Ce) Ca6(Fe2+,Mn2+)Y3REE7(SiO4)3(PO4)(B3Si3O18)(BO3)F11 1:11 trigonal R3m a = 10.804 c = 27.726 Z=3 2802.6 4.61 Uniaxial (-) 2011 [17]
Martinite (Na,◻,Ca)12Ca4(Si,S,B)14B2O38(OH,Cl)2F2·4H2O ~16:2 triclinic P1_ a = 9.5437 Å, b = 9.5349 Å, c = 14.0268 Å

α = 108.943°, β = 74.154°, γ = 119.780° Z=2

1038.1 2001 [18]
Odigitriaite CsNa5Ca5[Si14B2O38]F2 2:2 monoclinic C2/c a = 16.652 b = 9.598 c = 22.120 β = 92.87° Z=4 3,530.9 2.8 Biaxial nα = 1.502 nβ = 1.564 nγ = 1.576

2V: measured: 46°

Max birefringence: δ = 0.074

2015 [19]
Okanoganite-(Y) (Na,Ca)3(Y,Ce)12Si6B2O27F14 2:14 trigonal R3m a = 10.7108 c = 27.0398 Z=3 2,686.4 4.34 Uniaxial (-) nω = 1.753 nε = 1.740

Max birefringence: δ = 0.013

1979 [20]
Pertsevite-(F) Mg2(BO3)(F,OH) 1:1 orthorhombic Pna21 a = 20.49 b = 4.571 c = 11.89 Z=16 1113.6 3.12 Biaxial (+) nα = 1.609 nβ = 1.620 nγ = 1.642

2V: measured: 65° calculated: 71°

Max birefringence: δ = 0.033

2002 [21]
Piergorite-(Ce) Ca8(Ce,Th,La,Nd)2(Al0.5,Fe3+0.5)(◻,Li,Be)2Si6B8O36(OH,F)2 ~8:2 monoclinic P2/a a = 28.097 b = 4.777 c = 10.236 β = 96.81 Z=2 1364.2 3.67 Biaxial (-) nα = 1.717 nβ = 1.728 nγ = 1.735

2V: measured: 68° calculated: 77°

Max birefringence: δ = 0.018

2005 [22]
Popugaevaite Ca3[B5O6(OH)6]FCl2•8H2O 5:1 monoclinic Pm a = 8.705 b = 8.102 c = 14.812 β = 91.367 1044.4 2020 [23]
Proshchenkoite-(Y) Ca(Y,REE,Ca,Na,Mn)15Fe2+(P,Si)Si6B3O34F14 3:14 trigonal R3m a = 10.7527 c = 27.4002 2,743.6 2008 [24]
Rhabdoborite-(Mo) Mg12Mo6+1.33O6(BO3)6F2 6:2 hexagonal P63 a = 10.6304 c = 4.5637 446.63 2020 [25]
Rhabdoborite-(V) Mg12(V5+,Mo6+,W6+)1 · 5O6{[BO3]6-x[(P,As)O4]xF2-x} (x < 1) hexagonal P63 a = 10.6314 c = 4.5661 446.95 2018 [26]
Rhabdoborite-(W) Mg12(W6+,V5+)1 · 5O6{[BO3]6–x[(P,As)O4]xF2–x} (x < 1) hexagonal P63 a = 10.6366 c = 4.5701 447.78 2018 [27]
Sulfoborite Mg3[B(OH)4]2(SO4)(OH,F)2 ~2:2 Orthorhombic Biaxial (-) nα = 1.527 nβ = 1.536 nγ = 1.551

2V: measured: 79° , calculated: 78°

Max birefringence: δ = 0.024

1893 [28]
Tienshanite KNa3Na6Ca2Ba6Mn6(Ti4+,Nb)6B12Si36O114(O,OH,F)11 ~12:11 hexagonal P6/m a = 16.785 c = 10.454 Z=1 2550.7 Uniaxial (-) nω = 1.666 nε = 1.653

Max birefringence: δ = 0.013

1967 [29]
Vicanite-(Ce) (Ca,Ce,La,Th)15As5+(As3+0.5,Na0.5)Fe3+Si6B4O40F7 4:7 trigonal Uniaxial (-) nω = 1.757 nε = 1.722

Max birefringence: δ = 0.035

1991 [30]
Luinaite-(F) Na(Fe2+)3Al6(Si6O18)(BO3)3(OH)3F 3:1 2013 [31]
(Pb,Na)(Li,Al)3Al6(Si6O18)(BO3)3(OH)3(F,OH) 3:1 2009 [32]
Artificial
NBBF NaBe2BO3F2 C2 a=12.643 b=8.729 c=7.591 β=113.6° 768 nx=1.37 ny=1.474

birefringence 0.07 -.10

UV limit 1550 Å

1993 [33]
Al6(BO3)5F3 [34]
Al8(BO3)4(B2O5)F8 3:4 704.70 tetragonal P42/nmc a=9.134 c=19.112 Z=4 1595 2.935 UV limit <190 nm [34]
potassium beryllium borate fluoride KBBF KBe2BO3F2 1:2 153.93 R32 a=4.4261 c=18.7617 Z=3 318.30 2.409 [33][35]
Li5Ca9(BO3)7F2 7:2 P1
NaCaBe2B2O6F 2:1 217.71 Cc a=4.6232 b=8.008 c=14.182 Z=4 525.1 2.75 2011 [36][37]
KCaBe2B2O6F 2:1 467.64 P3_1c a=4.705 c=14.554 Z=2 279.1 2.783 2011 [37]
KCaZn2(BO3)2F 2:1
RbBe2BO3F2 200.30 trigonal R32 a=4.4387 c=19.820 Z=3 338.17 2.951 colourless 2009 [38]
RbCaBe2B2O6F 2:1 R32 [36]
Rb18Mg6(B5O10)3(B7O14)2F 29:1 2944.81 monoclinic C2/c a=11.06 b=19.70 c=31.01 β=90.13 Z=4 6750 2.896 2015 [39]
hexalithium rubidium diborate fluoride Li6RbB2O6F 2:1 263.73 orthorhombic Pnma a=8.41 b=15.96 c=5.08 Z=2 682 2.568 2014 [40]
NaBe3Sr3(BO3)3F4 R3m
KSrBe2B2O6F 2:1 281.36 P63/m a=4.765 c=15.050 Z=2 296.0 3.157 2011 [37]
strontium beryllium borate fluoride SBBOF Sr3[(BexB1–x)3B3O10][Be(O1–xFx)3] x = 0.30 ~3:0.9 545.93 trigonal R3m a = 10.318, c = 8.396 Z = 3 774.1 3.513 SHG 2.2×KDP 2016 [41]
K3SrLi2Al4B6O20F 6:1 [34]
CdZn2KB2O6F 2:1
Cd8B5O15F 5:1 Fd3̅m a = 13.972(3) Å, and Z = 8 2016 [42]
CsBe2BO3F2 247.74 trigonal R32 a=4.4575 c=21.310 Z=3 366.7 3.366 colourless 2009 [38]
CsCaBe2B2O6F R32 [36]
Cs18Mg6(B5O10)3(B7O14)2F 29:1 3798.73 monoclinic C2/c a=11.234 b=20.11 c=32.12 β=90.225 Z=4 7257 3.476 2015 [39]
Ba5(BO3)3F 2:1 [43]
Li2BaSc(BO3)2F 2:1 332.80 hexagonal P63/m a=4.895 c=14.346 297.7 3.713 [44]
LiBa12(BO3)7F4 7:4 I4/mcm
NaBa12(BO3)7F4 7:4 I4/mcm
BaAl(BO3)F2 [34]
K5Ba10(BO3)8F 8:1 2058.38 trigonal R3̅c a = 15.293 c = 22.699 Z = 6 4597.4 4.461 band gap 6.05 eV 205 nm cutoff 2016 [36]
KMg2Ba7B14O28F5 14:5 1743.44 monoclinic C2/c a=16.638 b=13.609 c=15.214 β=121.309 Z=4 2943.3 3.934 colourless 2010 [45]
K3BaLi2Al4B6O20F 6:1 [34]
Ba3Zn(BO3)(B2O5)F 3:1 656.82 monoclinic P21/c a=15.179 b=7.006 c=8.763 β=100.148 Z=4 917.4 4.775 colourless 2016 [46]
Ba4Zn2(BO3)2(B2O5)F2 4:2 937.34 monoclinic C2/c _a=20.39 b=4.998 c=13.068 β=92.59 Z=4 1330.7 4.679 colourless 2016 [46]
Rb3SrLi2Al4B6O20F 6:1 [34]
Gd4(BO2)O5F 1:1 orthorhombic Pmmn a=15.746 b=3.8142 c=6.609 Z=2 396.9 6.45 colourless [47]
Gd2(BO3)F3 1:3
Gd3(BO3)2F3 2:3
Gd4[B4O11]F2 4:2
Eu5(BO3)3F 3:1 955.1 orthorhombic Pnma a=7.225 b=14.124 c=9.859 Z=4 1006.1 6.306 yellow 2010 [48]
TlBe2BO3F2 319.20 Trigonal R32 a=4.4387 c=19.942 Z=3 340.27 4.673 colourless 2009 [38]
LiBa2Pb(BO3)2F 2:1 625.32 orthorhombic Pmmn a=5.487 b=15.97 c=4.034 353.4 5.887 colourless [44]

References[edit]

  1. ^ "Arrheniusite-(Ce): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  2. ^ "Berborite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  3. ^ "Britvinite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  4. ^ "Byzantievite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  5. ^ "Cappelenite-(Y): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  6. ^ "Fluoborite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  7. ^ "Fluor-buergerite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  8. ^ "Fluor-dravite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  9. ^ "Fluor-elbaite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  10. ^ "Fluor-feruvite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  11. ^ "Fluor-liddicoatite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  12. ^ "Fluor-schorl: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  13. ^ "Fluor-tsilaisite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  14. ^ "Fluor-uvite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  15. ^ "Hellandite-(Yb): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  16. ^ "Jeremejevite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  17. ^ "Laptevite-(Ce): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  18. ^ "Martinite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  19. ^ "Odigitriaite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  20. ^ "Okanoganite-(Y): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-25.
  21. ^ "Pertsevite-(F): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-26.
  22. ^ "Piergorite-(Ce): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-26.
  23. ^ "Popugaevaite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-26.
  24. ^ "Proshchenkoite-(Y): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-26.
  25. ^ "Rhabdoborite-(Mo): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-26.
  26. ^ "Rhabdoborite-(V): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-26.
  27. ^ "Rhabdoborite-(W): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-26.
  28. ^ "Sulfoborite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-26.
  29. ^ "Tienshanite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-26.
  30. ^ "Vicanite-(Ce): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-26.
  31. ^ "Unnamed (F-analogue of Luinaite-(OH)): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-26.
  32. ^ "Unnamed (Pb-analogue of Fluor-liddicoatite): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-26.
  33. ^ a b Mei, Linfeng; Wang, Yebin; Chen, Chunagtian (January 1994). "Crystal structure of sodium beryllium borate fluoride". Materials Research Bulletin. 29 (1): 81–87. doi:10.1016/0025-5408(94)90108-2.
  34. ^ a b c d e f Wang, Ya; Han, Jian; Huang, Junben; Pan, Shilie (2020). "Al8(BO3)4(B2O5)F8: A F-Containing Aluminium Borate Featuring Two Types of Isolated B-O Groups". Inorganic Chemistry. 59 (1): 810–817. doi:10.1021/acs.inorgchem.9b03067. PMID 31877030.
  35. ^ Ye, Ning; Tang, Dingyaun (August 2006). "Hydrothermal growth of KBe2BO3F2 crystals". Journal of Crystal Growth. 293 (2): 233–235. Bibcode:2006JCrGr.293..233Y. doi:10.1016/j.jcrysgro.2006.05.038.
  36. ^ a b c d Liu, Lili; Yang, Yun; Jing, Qun; Dong, Xiaoyu; Yang, Zhihua; Pan, Shilie; Wu, Kui (2016-08-25). "K 5 Ba 10 (BO 3 ) 8 F: A New Potassium Barium Borate Fluoride with a Perovskite-Like Structure". The Journal of Physical Chemistry C. 120 (33): 18763–18770. doi:10.1021/acs.jpcc.6b05489. ISSN 1932-7447.
  37. ^ a b c Huang, Hongwei; Yao, Jiyong; Lin, Zheshuai; Wang, Xiaoyang; He, Ran; Yao, Wenjiao; Zhai, Naixia; Chen, Chuangtian (2011-12-27). "Molecular Engineering Design to Resolve the Layering Habit and Polymorphism Problems in Deep UV NLO Crystals: New Structures in MM′Be 2 B 2 O 6 F (M═Na, M′═Ca; M═ K, M′═Ca, Sr)". Chemistry of Materials. 23 (24): 5457–5463. doi:10.1021/cm202870q. ISSN 0897-4756.
  38. ^ a b c McMillen, Colin D.; Hu, Jia; VanDerveer, Donald; Kolis, Joseph W. (2009-08-01). "Trigonal structures of A Be 2 BO 3 F 2 ( A = Rb, Cs, Tl) crystals". Acta Crystallographica Section B Structural Science. 65 (4): 445–449. doi:10.1107/S0108768109024161. ISSN 0108-7681. PMID 19617679.
  39. ^ a b Wang, Zheng; Zhang, Min; Su, Xin; Pan, Shilie; Yang, Zhihua; Zhang, Hui; Liu, Lu (2015-01-19). "Q 18 Mg 6 (B 5 O 10 ) 3 (B 7 O 14 ) 2 F (Q=Rb and Cs): New Borates Containing Two Large Isolated Polyborate Anions with Similar Topological Structures". Chemistry - A European Journal. 21 (4): 1414–1419. doi:10.1002/chem.201404738. PMID 25414057.
  40. ^ Wu, Hongping; Yu, Hongwei; Bian, Qiang; Yang, Zhihua; Han, Shujuan; Pan, Shilie (2014-12-15). "Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method". Inorganic Chemistry. 53 (24): 12686–12688. doi:10.1021/ic502625b. ISSN 0020-1669. PMID 25437774.
  41. ^ Yu, Na; Wang, Shichao; Ye, Ning; Liang, Fei; Lin, Zheshuai; Luo, Min; Poeppelmeier, Kenneth R. (2016-07-12). "A Deep-Ultraviolet Nonlinear Optical Crystal: Strontium Beryllium Borate Fluoride with Planar Be(O/F) 3 Groups". Chemistry of Materials. 28 (13): 4563–4571. doi:10.1021/acs.chemmater.6b01111. ISSN 0897-4756.
  42. ^ Yang, Yun; Dong, Xiaoyu; Pan, Shilie (2016). "New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method". Dalton Transactions. 45 (16): 7008–7013. doi:10.1039/C6DT00621C. ISSN 1477-9226. PMID 26988597.
  43. ^ Rashchenko, Sergey V.; Bekker, Tatyana B.; Bakakin, Vladimir V.; Seryotkin, Yurii V.; Kokh, Alexander E.; Gille, Peter; Popov, Arthur I.; Fedorov, Pavel P. (4 July 2013). "A new mechanism of anionic substitution in fluoride borates". Journal of Applied Crystallography. 46 (4): 1081–1084. doi:10.1107/S0021889813015756.
  44. ^ a b Chen, Yanna; Zhang, Min; Hu, Cong; Wu, Hongping; Yang, Zhihua; Pan, Shilie (2018-10-17). "Li 2 BaSc(BO 3 ) 2 F and LiBa 2 Pb(BO 3 ) 2 F with Layered Structures featuring Special Li−O/F Configurations". Chemistry - A European Journal. 24 (58): 15477–15481. doi:10.1002/chem.201804126. PMID 30230058.
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  47. ^ Höppe, Henning A. (1 November 2015). "Gd4(BO2)O5F – a gadolinium borate fluoride oxide comprising a linear BO2 moiety". Zeitschrift für Naturforschung B. 70 (11): 769–774. doi:10.1515/znb-2015-0112. S2CID 197372271.
  48. ^ Kazmierczak, Karolina; Höppe, Henning A. (June 2010). "Synthesis, Crystal Structure and Optical Spectra of Europium Borate Fluoride Eu5(BO3)3F". European Journal of Inorganic Chemistry. 2010 (18): 2678–2681. doi:10.1002/ejic.201000105.
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