User:OrganoMetallurgy/Drafts/B10H10 -2
 | This is a draft article. It is a work in progress open to editing by anyone. Please ensure core content policies are met before publishing it as a live Wikipedia article. Find sources: Google (books · news · scholar · free images · WP refs) · FENS · JSTOR · TWL Last edited by SporkBot (talk | contribs) 6 years ago. (Update) |
| Identifiers | |
|---|---|
| Properties | |
| B10H10 | |
| Molar mass | 118.18 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
| |
non-chembox sections[edit]
Decaborate, B10H102−, is a closo borane anion. It is t dodecaborate. Its stucture was first reported in 1959 on the basis of its nmr spectrum. 10.1021/ja01530a073 Possibly/probably first synthesized by the same group in 1959 10.1021/ja01529a077
Structure[edit]
Bicapped square antiprism
Synthesis[edit]
from decaborane Reaction of decaborane with triethylamine in refluxing benzene produces triethylammonium decaborate
From borohydride Pyrolysis of tetraethylammonium borohydride at 185 °C produces tetraethylammonium decaborate in up to 94% yield, but in a manner strongly dependent on the exact conditions.
Reactions[edit]
Easily oxidized in aqueous acid. Halogenation
Applications[edit]
References[edit]
10.1135/cccc2010054