Zirconium(IV) acetate
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| Identifiers | |
|---|---|
| ECHA InfoCard | 100.021.982 |
CompTox Dashboard (EPA)
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| Properties | |
| C24H40O32Zr6 | |
| Molar mass | 1387.896 g·mol−1 |
| Appearance | white solid |
| soluble | |
| Related compounds | |
Related compounds
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zirconium dioxide, zirconium(IV) chloride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Zirconium acetate usually refers to the chemical formula Zr6O4(OH)4(O2CCH3)12. It forms by the reaction of zirconyl chloride and acetate. Claims of Zr(O2CCH3)4[1] have been superseded by experiments using X-ray crystallography.[2]
The species Zr6O4(OH)4(O2CCH3)12 is a common precursor to metal-organic frameworks (MOFs).[3]
References[edit]
- ^ Pavlov, V. L.; Lysenko, Yu. A.; Kalinichenko, A. A. Synthesis and properties of zirconium tetraacetate.(in Russian) Zhurnal Neorganicheskoi Khimii, 1972. 17(12). ISSN 0044-457X
- ^ Hennig, Christoph; Weiss, Stephan; Kraus, Werner; Kretzschmar, Jerome; Scheinost, Andreas C. (2017). "Solution Species and Crystal Structure of Zr(IV) Acetate". Inorganic Chemistry. 56 (5): 2473–2480. doi:10.1021/acs.inorgchem.6b01624. PMID 28199091.
- ^ Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni; Guillou, Nathalie; Lamberti, Carlo; Bordiga, Silvia; Lillerud, Karl Petter (2008). "A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability". Journal of the American Chemical Society. 130 (42): 13850–13851. doi:10.1021/ja8057953. PMID 18817383.
https://doi.org/10.1021/acs.inorgchem.6b01624 Copyright © 2017 American Chemical Society RIGHTS & PERMISSIONS Subscribed Access Article Views 3592 Altmetric 5 Citations 57 LEARN ABOUT THESE METRICS Share
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RIS PDF (2 MB) OpenURL UNIV ILLINOIS URBANA-CHAMPAIGNSupporting Info (2)»Supporting Information SUBJECTS:Cluster chemistry, Go to Inorganic Chemistry Inorganic Chemistry Abstract
Complex formation and the coordination of zirconium with acetic acid were investigated with Zr K-edge extended X-ray absorption fine structure spectroscopy (EXAFS) and single-crystal diffraction. Zr K-edge EXAFS spectra show that a stepwise increase of acetic acid in aqueous solution with 0.1 M Zr(IV) leads to a structural rearrangement from initial tetranuclear hydrolysis species [Zr4(OH)8(OH2)16]8+ to a hexanuclear acetate species Zr6(O)4(OH)4(CH3COO)12.