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CLD chromophore

From Wikipedia, the free encyclopedia
CLD-1
Names
IUPAC name
2-[4-[(E,3E)-3-[3-[(E)-2-[4-[bis[2-[tert-butyl(dimethyl)silyl]oxyethyl]amino]phenyl]ethenyl]-5,5-dimethylcyclohex-2-en-1-ylidene]prop-1-enyl]-3-cyano-5,5-dimethylfuran-2-ylidene]propanedinitrile
Other names
CLD-1
Identifiers
3D model (JSmol)
ChemSpider
  • CLD-1: InChI=1S/C45H64N4O3Si2/c1-42(2,3)53(11,12)50-26-24-49(25-27-51-54(13,14)43(4,5)6)38-22-20-34(21-23-38)18-19-36-28-35(29-44(7,8)30-36)16-15-17-40-39(33-48)41(37(31-46)32-47)52-45(40,9)10/h15-23,28H,24-27,29-30H2,1-14H3/b17-15+,19-18+,35-16-
    Key: PYNHPJZBYGNOPU-ONTZPWRJSA-N
  • CLD-1: CC1(CC(=C/C(=C/C=C/C2=C(C(=C(C#N)C#N)OC2(C)C)C#N)/C1)/C=C/C3=CC=C(C=C3)N(CCO[Si](C)(C)C(C)(C)C)CCO[Si](C)(C)C(C)(C)C)C
Properties
C31H32N4O
Molar mass 476.61
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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CLD-1 is a vibrant blue dye originally synthesized for application in nonlinear electro-optics.[1]

References

[edit]
  1. ^ CHENG ZHANG and Larry R. Dalton (2001). "Low Vπ Electrooptic Modulators from CLD-1: Chromophore Design and Synthesis, Material Processing, and Characterization". Chem. Mater. 13 (9): 3043–3050. doi:10.1021/cm010463j.