Frederick W. Stavely
Frederick W. Stavely (1894-1976) was a chemical research scientist who discovered polyisoprene.
Career[edit]
In 1950, Stavely served as chairman of the American Chemical Society Rubber Division.[1]
In 1953, Stavely was working at the Firestone Tire & Rubber Company when he discovered polyisoprene. At the time he was investigating the reaction of butyl lithium on butadiene and discovered that polymerization of isoprene with metallic lithium produced polyisoprene (dubbed coral rubber[2] because of its appearance) with a high cis content.[3] High cis content is associated with enhanced strain crystallization, important during World War II because other synthetics did not exhibit the crystallization effect.
In 1972, Stavely received the Charles Goodyear Medal in recognition of this discovery.[4]
References[edit]
- ^ "Audio interview with FW Stavely".
- ^ Stavely, F. W. (1956). "Coral rubber—a cis-1, 4-polyisoprene". Rubber Chemistry and Technology. 29 (3): 673–686. doi:10.5254/1.3542582.
- ^ Morris, Peter J. T. (2005). Polymer Pioneers: A Popular History of the Science and Technology of Large Molecules. Chemical Heritage Foundation. p. 88. ISBN 9780941901031.
- ^ Stavely, F. W. (1972). "Lithium Polymerization Catalysts. Charles Goodyear Medal Address—1972". Rubber Chemistry and Technology. 45 (4): 56–60. doi:10.5254/1.3542894.
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