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Promethium iodate

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Promethium iodate
Identifiers
3D model (JSmol)
  • InChI=1S/3HIO3.Pm/c3*2-1(3)4;/h3*(H,2,3,4);/q;;;+3/p-3
    Key: OTVRQOHWWGIUPQ-UHFFFAOYSA-K
  • anhydrous: [Pm+3].O=I(=O)[O-].O=I(=O)[O-].O=I(=O)[O-]
  • monohydrate: [Pm+3].O=I(=O)[O-].O=I(=O)[O-].O=I(=O)[O-].O
Properties
Pm(IO3)3
Molar mass 669.71
Density 5.00 g·cm−3 (hydrate)[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Promethium iodate is an inorganic compound with the chemical formula Pm(IO3)3. It can be obtained by reacting with potassium iodate, ammonium iodate or a slight excess of iodic acid and Pm3+ solution and precipitating it.[2] Its hydrate, Pm(IO3)3·H2O, crystallizes in the P21 space group, with unit cell parameters a=10.172±13, b=6.700±20, c=7.289±24 Å, β=113.1±0.2°.[1]

References

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  1. ^ a b Abrahams, S.C.; Bernstein, J.L.; Nassau, K. (Jan 1976). "Transition metal iodates. VII. Crystallographic and nonlinear optic survey of the 4f-iodates". Journal of Solid State Chemistry. 16 (1–2): 173–184. Bibcode:1976JSSCh..16..173A. doi:10.1016/0022-4596(76)90020-7.
  2. ^ Yi, Xianwu (1992). 1.3.3 Compounds with oxidation state +3. Series of Inorganic Chemistry - Vol 7 - Scandium, Rare earth elements (First ed.). Beijing: Science Press. ISBN 978-7-03-030574-9. OCLC 759498851.

External reading

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