User:Bdushaw/BrietRabi

Breit, G.; Rabi, I.I. (1934). "On the interpretation of present values of nuclear moments". Physical Review 46: 230.

References

1 A. Lande, Phys. Rev. 44, 1028 (1933).

2 B.Venkataschar and T. Subbaraya, Zeits. f. Physik 85, 264 (1933).

3 D. R. Inglis and A. Lande, Phys. Rev. 45, 842 (1934).

4 H. Kallmann and A. Schueler, Zeits. f. Physik 88, 210 (1934).

5 H. Schueler, Zeits. f. Physik 88, 323 (1934).

6 H. Schueler and H. Westmeyer, Naturwiss. 21, 674 (1933),

7 T. Tamm and S, Altschuler, Comptes Rendus de L' Academic des Sciences de l' U.R.S.S. 1, 458 (1934).

8 Stern, Estermann and Frisch, Zeits. f. Physik 85, 4, 17 (1933).

9 Rabi, Kellogg and Zacharias, Phys. Rev. 45, 761 (1934).

On the Interpretation of Present Values of Nuclear Moments

Various writers (1-7) have published speculations gn the magnetic moment and the nature of the neutron and proton. In view of the discordant results it appears proper to discuss the reliability of the g values for different nuclei as well as the plausibility of the explanations proposed from the point of view of nuclear structure.

(a} It is believed by Inglis and Lande(3) that the disagreement between Lande's assumed value gs =4 for the proton g factor, the molecular beam value(8) 5.0+10 percent, and the atomic beam value(9) 6.4+10 percent is to be attributed to the crudities of the theory used in all three cases. As far as we know this objection cannot apply to the R. K. Z. value. The only essential ppints presupposed in the theory of the experiment are: (1) the possibility of describing the interaction of the electron and the nucleus by assuming a nuclear magnetic moment, (2) the sufficient validity of Dirac's equation for a single electron as applied to hydrogen. It is possible that one or both of these suppositions are incorrect, but it seems impossible to discuss the problem definitely without either. The agreement between the S. E. F. and the R. K. Z. value may be regarded as a support of both. It should be remembered that the S. E. F. value is obtained by a direct measurement of the force on the magnetic moment of the proton and does not depend on interactions between electrons and protons a short distance apart. The corrections for the rotational magnetic moment of the molecule were made experimentally by using parahydrogen. The only vital assumption involved is that of the constancy of this magnetic moment to the corresponding mechanical angular momentum. We see no reason for seriously questioning this.

On the other hand, the nuclear g values used. by Lande are questionable, With the exception of g =2.19 for Li(7) they are all obtained on the supposition that the many electron problem presented by an atom is approximated with sufticient accuracy by replacing the effect of all but the valence electrons by a suitable central field. In some casqs corrections for perturbations have been made. In no case has a complete calculation been carried out. The magnitude of the error introduced by this assumption is at present unknown and there appears to be no valid reason for supposing it to be small.

It is possible to eliminate our lack of knowledge of absolute nuclear g values by paying attention to the ratios of the g factors of isotopes. The atomic wave functions cancel out in such a calculation. It is of interest to discuss such ratios for Z odd and M' odd by using Lande's picture of i and p, as due to proton having a definite orbital angular momentum l. For Rb the only reasonable assignment of l is l = 1 for Rb87 and l =3 for Rb85. Other assignments lead to impossible ratios of g(87)/g(85) or else to wrong signs of g(87) or g(85). Using the experimental value g(87)/g(85) =3.46 one obtains gs =3.97 which is in excellent agreement with Lande's gs =4 but disagrees violently with S. E. F.'s g, =5 or R. K. Z.'s gs =6, these values of g, would require g(87)/g(85) =5.4, 9.3, respectively. Both of these values are excluded by the high accuracy of Kopfermann's experirnents. For Sb the experimental value g(121)/g(123) =1.80 may be accounted for either by gs =3 with l =2 for Sb121 (i=5/2) and 1=4 for Sb123 (i=7/2) or else by gs =—3, l =3 for Sb121 and Sb123. The latter choice is in disagreement with Rb and so is g, =3 because gs =4 gives g(121)/g(123) =2.4 which can hardly be mistaken for 1.80. For Ga there appears to be no reasonable way of accounting for g(71)/ g(69) = 1.27, on Lande's picture.(1)

The theoretical values given in Table III of Tamm and Altschuler appear to satisfy the isotope ratio for Sb very accurately giving g(121)/g(123) =1.79 as compared with the experimental value 1.80. This agreement is due, however, to a numerical error present in this table and in the corresponding table of Lande. For Sb123 one cannot use lp=3 because i =7/2 was used to obtain g=0.60 and for g (proton spin) =gsp=4 one would have g(123) =10/7=1.43 as compared with the observed 0.60. On the other hand, using lp=4, one gets g(123) =0.67. In order to obtain reasonable agreement with the observed g(121) one has to use lp=4 in Sb121 coupled to sp to give jp=7/2 which is then coupled to jn =1 to give i=5/2. One obtains a theoretical g=1.00 and a theoretical g(121)/g(123) =1.50 which is in poor agreement with the observed 1.80. For Ga the table of Tamm and Altschuler gives for g(71)/g(69) the values 1.50 theoretically which compares poorly with the experimental 1.28. Kallmann and Schueler obtain satisfactory ratios for Rb and Sb but for Ga the theoretical 1.36 is too large. Even if this discrepency were removed the value gsp=4 used by K. S. is in definite contradiction with S. E. F. and R. K. Z. as well as with the g factor for Li7.

It should be emphasized that in the above comparison the uncertain features of theoretical calculations have been eliminated. Thus the data available at present appear to indicate a variable g, according to all the schemes proposed. None of the above values are in agreement with g =2.2 for Li~ which leads to either gs =4.6 or gs =—5.0. Either of these values agrees with the measurements of S. E. F. and of R. K. Z. since the sign of g, is left undetermined by them. On the other hand, adjusting g(Li7) to be 2 as is desired by Lande, implies an accuracy of only 10 percent in the theoretical calculations. The relative simplicity of the electronic configurations dealt with suggests a much higher accuracy.

(b) The attempt at a conclusion that the neutron is not an elementary particle from the sign of its g factor appears to be premature. It is well known that interaction terms of Pauli's type can describe a particle with an arbitrary magnetic moment so that either sign of the g factor is in agreement with the view that the neutron is an elementary particle. Further, either sign can be explained by supposing that the neutron is composite: a negative value can be explained by saying neutron =proton+electron, a positive value one could explain by saying neutron =neutron' +electron+positron.

The sense in which electrons or positrons may be said to exist in a nucleus is very obscure. We doubt whether much meaning may be ascribed to theories making detailed pictures of the composition of the neutron or proton.

(c) According to the usual ideas of nuclear structure the constitution of a nucleus resembles that of a polyatomic molecule or else of a liquid. It is questionable whether there is much meaning to a central field which one must necessarily assume in order to assign an orbital quantum number to a particle under these conditions. Even if the central field picture applies it is questionable whether the core may be considered as having a constant g factor as is done by Kallmann and Schueler. It is also questionable whether the coupling order p(nn) used by Tamm and Altschuler is consistent with the generally supposed importance of the pn bond. One would rather suppose that (pn}n is a more probable coupling possibility.

In the table of Lande for nuclei with odd Z and odd M some nuclei have lp>jp and others lp<jp.Presumably one of these possibilities corresponds to a lower energy level than the other. The energy difference between jp=lp+1/2, and jp=lp—1/2 may be supposed to be of the order of the magnetic interaction energy of two nuclear magnetons located at a distance of 10^-13 from each other. Its order of magnitude is several hundred volts. The probability of magnetic dipole radiation from the higher to the lower of these levels is such that the mean life would be ~1/50 sec. if DELTA W=200 volts. It is thus difficult to reconcile the known stability of a number of nuclei with the above theories of nuclear moments.

G. BREIT

New York University

I. I. RABI

Columbia University

July 21, 1934.