User:Benjah-bmm27/degree/2/DFW

Organometallics, DFW

A cyclopentadienyl complex, [Cp₂W(CO)₂], with two different hapticities: η⁵-Cp (top) and η³-Cp (bottom)

A trinuclear anionic nickel complex featuring triply bridging carbonyl ligands, [(η⁵-CpNi)₃(μ₃-CO)₂]⁻

"Organo-Transition Metal Chemistry" http://www.ilpi.com/organomet/

• Organometallic chemistry
• d electron count, electron counting
• 18-Electron rule
• Metal carbonyls;
  • Chromium hexacarbonyl, [Cr(CO)₆]
  • Dimanganese decacarbonyl, [Mn₂(CO)₁₀]
  • Iron pentacarbonyl, [Fe(CO)₅]
  • Dicobalt octacarbonyl, [Co₂(CO)₈]
  • Nickel tetracarbonyl, [Ni(CO)₄]
• Homoleptic means all ligands the same
• Bridging ligands, e.g. CO in [(CpNi)₃(CO)₂]⁻ – Jmol
• Fischer-Tropsch process
• Fluxionality
• Berry mechanism
• Mond process
• π backbonding: Dewar-Chatt-Duncanson model
• Phosphine
• Beta-hydride elimination
• Migratory insertion
• Hapticity (η notation)
• Carbenes, transition metal carbene complexes
• Zeise's salt
• 1,3-Butadiene as a ligand

• Ferrocene
• Bis(benzene)chromium
• Migratory insertion, Oxidative addition, Reductive elimination
• Indenyl ligand, indenyl effect